Steric-effect-induced enhancement of electrical-double-layer overlapping phenomena

Siddhartha Das, Suman Chakraborty

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54 Citations (Scopus)
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Abstract

In this paper, we demonstrate that nontrivial interactions between steric effect and electrical-double-layer (EDL) overlap phenomena may augment the effective extent of EDL overlap in narrow fluidic confinements to a significant extent by virtue of rendering the channel centerline potential tending to the ζ potential in a limiting sense as the steric effect progressively intensifies. Such a behavior may result in a virtually uniform (undiminished) magnitude of the EDL potential across the entire channel height and may cause lowering of the total charge within the EDL.
Original languageEnglish
Article number012501
Number of pages4
JournalPhysical review E: Statistical, nonlinear, and soft matter physics
Volume84
Issue number1
DOIs
Publication statusPublished - 2011

Keywords

  • METIS-278501
  • IR-78898

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