Structural, optical and electronic properties of LaMgHx switchable mirrors

J. Isidorsson, I.A.M.E. Giebels, Ernst S. Kooij, N.J. Koeman, J.H. Rector, A.T.M. van Gogh, R. Griessen

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Abstract

Structural, optical and electronic properties of lanthanum magnesium alloy thin films are studied in situ in real time during hydrogenation. X-ray data show that the as-deposited films contain the intermetallic phase LaMg with CsCl structure as well as fcc β-La and fcc LaHx. Hydrogenation initiates a transformation of β-La to β-LaHx, while the intermetallic phase disproportionates. The fcc structure stays intact during further uptake of hydrogen up to LaH3, and Mg transforms to the rutile structure of MgH2. During hydrogen absorption the alloys change from a good conducting, metallic state with high reflectance, to a transparent color neutral insulator with a band-gap of about 3 eV.
Original languageUndefined
Pages (from-to)2179-2185
Number of pages7
JournalElectrochimica acta
Volume46
Issue number13-14
DOIs
Publication statusPublished - 2001

Keywords

  • X-ray
  • Metal–insulator transition
  • IR-73667
  • Optical properties
  • LaMg hydride
  • Switchable mirror
  • METIS-202535

Cite this

Isidorsson, J., Giebels, I. A. M. E., Kooij, E. S., Koeman, N. J., Rector, J. H., van Gogh, A. T. M., & Griessen, R. (2001). Structural, optical and electronic properties of LaMgHx switchable mirrors. Electrochimica acta, 46(13-14), 2179-2185. https://doi.org/10.1016/S0013-4686(01)00373-5