TY - JOUR

T1 - Structure and formation of a gel of colloidal disks

AU - Kroon, Mark

AU - Vos, Willem L.

AU - Wegdam, Gerard H.

PY - 1998/2/1

Y1 - 1998/2/1

N2 - We have performed static scattering experiments on the transition in time from a fluidlike sol to a solidlike gel of a suspension of disk-shaped charged colloidal particles. The combination of static light scattering and small angle x-ray scattering probes more than three orders of magnitude in the scattering vector [Formula Presented]. At the smallest [Formula Presented] the static structure factor [Formula Presented] shows a [Formula Presented] dependence in both the sol and gel state. The algebraic exponent [Formula Presented] evolves from [Formula Presented] to [Formula Presented] during the gelation. We find that the sol is not comparable to a simple liquid but rather to a low-viscosity precursor of the gel. At intermediate [Formula Presented] a plateau connects this regime to the form factor [Formula Presented] of the colloidal disks, which is observed at the largest [Formula Presented]. On the plateau a small peak related to nearest-neighbor correlations is observed, which decays before gelation occurs. After application of shear on the suspensions we have observed the rapid formation of nematiclike order of the colloidal disks. This order decays in time due to reorientation of the colloidal disks while the final gel state is reached. The formation of the gel does not proceed via aggregation to form ever larger clusters. Based on our findings we propose that reorientation of the charged particles is the mechanism by which the gelation occurs.

AB - We have performed static scattering experiments on the transition in time from a fluidlike sol to a solidlike gel of a suspension of disk-shaped charged colloidal particles. The combination of static light scattering and small angle x-ray scattering probes more than three orders of magnitude in the scattering vector [Formula Presented]. At the smallest [Formula Presented] the static structure factor [Formula Presented] shows a [Formula Presented] dependence in both the sol and gel state. The algebraic exponent [Formula Presented] evolves from [Formula Presented] to [Formula Presented] during the gelation. We find that the sol is not comparable to a simple liquid but rather to a low-viscosity precursor of the gel. At intermediate [Formula Presented] a plateau connects this regime to the form factor [Formula Presented] of the colloidal disks, which is observed at the largest [Formula Presented]. On the plateau a small peak related to nearest-neighbor correlations is observed, which decays before gelation occurs. After application of shear on the suspensions we have observed the rapid formation of nematiclike order of the colloidal disks. This order decays in time due to reorientation of the colloidal disks while the final gel state is reached. The formation of the gel does not proceed via aggregation to form ever larger clusters. Based on our findings we propose that reorientation of the charged particles is the mechanism by which the gelation occurs.

UR - http://www.scopus.com/inward/record.url?scp=85006406315&partnerID=8YFLogxK

U2 - 10.1103/PhysRevE.57.1962

DO - 10.1103/PhysRevE.57.1962

M3 - Article

AN - SCOPUS:85006406315

VL - 57

SP - 1962

EP - 1970

JO - Physical review E: covering statistical, nonlinear, biological, and soft matter physics

JF - Physical review E: covering statistical, nonlinear, biological, and soft matter physics

SN - 2470-0045

IS - 2

ER -