Surface-confined metallodendrimers: isolated nanosize molecules

B.H. Huisman; Holger Schönherr; W.T.S. Huck; Wilhelm T.S. Huck; A. Friggeri; H.J. van Manen; E. Menozzi; Edoardo Menozzi; Gyula J. Vancso; F.C.J.M. van Veggel; David Reinhoudt

doi:10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

Surface-confined metallodendrimers: isolated nanosize molecules

B.H. Huisman, Holger Schönherr, W.T.S. Huck, Wilhelm T.S. Huck, A. Friggeri, H.J. van Manen, E. Menozzi, Edoardo Menozzi, Gyula J. Vancso, F.C.J.M. van Veggel, David Reinhoudt

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200×200 nm2 after 20 h).

Original language	Undefined
Pages (from-to)	2248-2251
Journal	Angewandte Chemie (international edition)
Volume	38
Issue number	38
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1
Publication status	Published - 1999

Keywords

METIS-106252
IR-11617

Access to Document

10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

Cite this

Huisman, B. H., Schönherr, H., Huck, W. T. S., Huck, W. T. S., Friggeri, A., van Manen, H. J., Menozzi, E., Menozzi, E., Vancso, G. J., van Veggel, F. C. J. M., & Reinhoudt, D. (1999). Surface-confined metallodendrimers: isolated nanosize molecules. Angewandte Chemie (international edition), 38(38), 2248-2251. https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

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abstract = "The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200×200 nm2 after 20 h).",

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author = "B.H. Huisman and Holger Sch{\"o}nherr and W.T.S. Huck and Huck, {Wilhelm T.S.} and A. Friggeri and {van Manen}, H.J. and E. Menozzi and Edoardo Menozzi and Vancso, {Gyula J.} and {van Veggel}, F.C.J.M. and David Reinhoudt",

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Huisman, BH, Schönherr, H, Huck, WTS, Huck, WTS, Friggeri, A, van Manen, HJ, Menozzi, E, Menozzi, E, Vancso, GJ, van Veggel, FCJM & Reinhoudt, D 1999, 'Surface-confined metallodendrimers: isolated nanosize molecules', Angewandte Chemie (international edition), vol. 38, no. 38, pp. 2248-2251. https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

TY - JOUR

T1 - Surface-confined metallodendrimers: isolated nanosize molecules

AU - Huisman, B.H.

AU - Schönherr, Holger

AU - Huck, W.T.S.

AU - Huck, Wilhelm T.S.

AU - Friggeri, A.

AU - van Manen, H.J.

AU - Menozzi, E.

AU - Menozzi, Edoardo

AU - Vancso, Gyula J.

AU - van Veggel, F.C.J.M.

AU - Reinhoudt, David

PY - 1999

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AB - The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200×200 nm2 after 20 h).

KW - METIS-106252

KW - IR-11617

U2 - 10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

DO - 10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

M3 - Article

SN - 1433-7851

VL - 38

SP - 2248

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JO - Angewandte Chemie (international edition)

JF - Angewandte Chemie (international edition)

IS - 38

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