Surface-confined metallodendrimers: isolated nanosize molecules

Bart-Hendrik Huisman; Holger Schönherr; Wilhelm T.S. Huck; Arianna Friggeri; Henk-Jan van Manen; Edoardo Menozzi; G. Julius Vancso; Frank C.J.M. van Veggel; David N. Reinhoudt

doi:10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

Surface-confined metallodendrimers: isolated nanosize molecules

Bart-Hendrik Huisman
, Holger Schönherr
, Wilhelm T.S. Huck
, Arianna Friggeri
, Henk-Jan van Manen
, Edoardo Menozzi
, G. Julius Vancso
, Frank C.J.M. van Veggel
, David N. Reinhoudt

Research output: Contribution to journal › Article › Academic › peer-review

46 Citations (Scopus)

19 Downloads (Pure)

Abstract

The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200×200 nm2 after 20 h).

Original language	English
Pages (from-to)	2248-2251
Journal	Angewandte Chemie (international edition)
Volume	38
Issue number	38
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1
Publication status	Published - 1999

Keywords

2020 OA procedure

Access to Document

10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

ArticleFinal published version, 134 KBLicence: Taverne

Cite this

Huisman, B.-H., Schönherr, H., Huck, W. T. S., Friggeri, A., van Manen, H.-J., Menozzi, E., Vancso, G. J., van Veggel, F. C. J. M., & Reinhoudt, D. N. (1999). Surface-confined metallodendrimers: isolated nanosize molecules. Angewandte Chemie (international edition), 38(38), 2248-2251. https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

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title = "Surface-confined metallodendrimers: isolated nanosize molecules",

abstract = "The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200{\texttimes}200 nm2 after 20 h).",

keywords = "2020 OA procedure",

author = "Bart-Hendrik Huisman and Holger Sch{\"o}nherr and Huck, \{Wilhelm T.S.\} and Arianna Friggeri and \{van Manen\}, Henk-Jan and Edoardo Menozzi and Vancso, \{G. Julius\} and \{van Veggel\}, \{Frank C.J.M.\} and Reinhoudt, \{David N.\}",

year = "1999",

doi = "10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1",

language = "English",

volume = "38",

pages = "2248--2251",

journal = "Angewandte Chemie (international edition)",

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}

TY - JOUR

T1 - Surface-confined metallodendrimers

T2 - isolated nanosize molecules

AU - Huisman, Bart-Hendrik

AU - Schönherr, Holger

AU - Huck, Wilhelm T.S.

AU - Friggeri, Arianna

AU - van Manen, Henk-Jan

AU - Menozzi, Edoardo

AU - Vancso, G. Julius

AU - van Veggel, Frank C.J.M.

AU - Reinhoudt, David N.

PY - 1999

Y1 - 1999

N2 - The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200×200 nm2 after 20 h).

AB - The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200×200 nm2 after 20 h).

KW - 2020 OA procedure

U2 - 10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

DO - 10.1002/(SICI)1521-3773(19990802)38:15<2248::AID-ANIE2248>3.0.CO;2-1

M3 - Article

SN - 1433-7851

VL - 38

SP - 2248

EP - 2251

JO - Angewandte Chemie (international edition)

JF - Angewandte Chemie (international edition)

IS - 38

ER -

Surface-confined metallodendrimers: isolated nanosize molecules

Abstract

Keywords

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