Synthesis of 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation

Arturo Arduini; Laura Domiano; Andrea Pochini; Andrea Secchi; Rocco Ungaro; Franco Ugozzoli; Oliver Struck; Willem Verboom; David N. Reinhoudt

doi:10.1016/S0040-4020(97)00097-5

Synthesis of 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation

Arturo Arduini, Laura Domiano, Andrea Pochini, Andrea Secchi, Rocco Ungaro, Franco Ugozzoli, Oliver Struck, Willem Verboom, David N. Reinhoudt

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Abstract

New methods to obtain 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation are described. The stereochemistry of the proximal double functionalization reaction is mainly governed by the solvent, the length of the polyether units and the base used to deprotonate the calix[4]arene.

Original language	English
Pages (from-to)	3767-3776
Journal	Tetrahedron
Volume	53
Issue number	10
DOIs	https://doi.org/10.1016/S0040-4020(97)00097-5
Publication status	Published - 1997

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@article{55897d80c5ef4fc7b2f5fc111186e712,

title = "Synthesis of 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation",

abstract = "New methods to obtain 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation are described. The stereochemistry of the proximal double functionalization reaction is mainly governed by the solvent, the length of the polyether units and the base used to deprotonate the calix[4]arene.",

author = "Arturo Arduini and Laura Domiano and Andrea Pochini and Andrea Secchi and Rocco Ungaro and Franco Ugozzoli and Oliver Struck and Willem Verboom and Reinhoudt, {David N.}",

year = "1997",

doi = "10.1016/S0040-4020(97)00097-5",

language = "English",

volume = "53",

pages = "3767--3776",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Ltd",

number = "10",

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TY - JOUR

T1 - Synthesis of 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation

AU - Arduini, Arturo

AU - Domiano, Laura

AU - Pochini, Andrea

AU - Secchi, Andrea

AU - Ungaro, Rocco

AU - Ugozzoli, Franco

AU - Struck, Oliver

AU - Verboom, Willem

AU - Reinhoudt, David N.

PY - 1997

Y1 - 1997

N2 - New methods to obtain 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation are described. The stereochemistry of the proximal double functionalization reaction is mainly governed by the solvent, the length of the polyether units and the base used to deprotonate the calix[4]arene.

AB - New methods to obtain 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation are described. The stereochemistry of the proximal double functionalization reaction is mainly governed by the solvent, the length of the polyether units and the base used to deprotonate the calix[4]arene.

U2 - 10.1016/S0040-4020(97)00097-5

DO - 10.1016/S0040-4020(97)00097-5

M3 - Article

SN - 0040-4020

VL - 53

SP - 3767

EP - 3776

JO - Tetrahedron

JF - Tetrahedron

IS - 10

ER -

Synthesis of 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation

Abstract

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