Synthesis of 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation

Arturo Arduini, Laura Domiano, Andrea Pochini, Andrea Secchi, Rocco Ungaro, Franco Ugozzoli, Oliver Struck, O. Struck, Willem Verboom, David Reinhoudt

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Abstract

New methods to obtain 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation are described. The stereochemistry of the proximal double functionalization reaction is mainly governed by the solvent, the length of the polyether units and the base used to deprotonate the calix[4]arene.
Original languageUndefined
Pages (from-to)3767-3776
JournalTetrahedron
Volume53
Issue number53
DOIs
Publication statusPublished - 1997

Keywords

  • METIS-105900
  • IR-10912

Cite this

Arduini, A., Domiano, L., Pochini, A., Secchi, A., Ungaro, R., Ugozzoli, F., ... Reinhoudt, D. (1997). Synthesis of 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation. Tetrahedron, 53(53), 3767-3776. https://doi.org/10.1016/S0040-4020(97)00097-5