Synthetische molekulare Hohlraume

Translated title of the contribution: Synthetic molecular cavities

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Abstract

A new strategy for the synthesis of molecular cavities was developed by the covalent linkage of relatively rigid macrocydes (calix[4]- and
resorcin[4]arenes) which themselves possess a permanent cavity. The stepwise coupling of the respective building blocks gives carceplexes
(host-guest compounds) which have trapped guest molecules in their interior. These carceplexes exhibit a novel type of stereoisomerism
(carceroisomerism) as a result of different orientations of the guest molecules inside the cavity. The convergent, cyclic combination of two calix[4]- and two resorcin[4]arene building blocks gives a large artifical receptor molecule (holand). The holand contains a permanent cavity of nanosize dimensions which is extremely rigid for its size.
Translated title of the contributionSynthetic molecular cavities
Original languageGerman
Pages (from-to)640-642
JournalGIT
Volume40
Issue number6
Publication statusPublished - 1996

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