Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]

Ole Göbel; Johan E. ten Elshof; A.M.M. Schreurs

doi:10.1524/zkri.2011.1401

Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]

Ole Göbel, Johan E. ten Elshof, A.M.M. Schreurs

Inorganic Materials Science

Research output: Contribution to journal › Article › Academic › peer-review

7 Citations (Scopus)

Abstract

The crystal structure of (TMA)2[TiF6] between –173 °C and 180 °C was refined on the basis of single crystal diffraction data. A phase transition from rhombohedral to cubic at approx. 142 °C was found by measuring the birefringence as a function of temperature, and confirmed by the refined crystal structures

Original language	English
Pages (from-to)	748-755
Number of pages	9
Journal	Zeitschrift für Kristallographie
Volume	226
Issue number	9
DOIs	https://doi.org/10.1524/zkri.2011.1401
Publication status	Published - 2011

Keywords

METIS-280145

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10.1524/zkri.2011.1401

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title = "Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]",

abstract = "The crystal structure of (TMA)2[TiF6] between –173 °C and 180 °C was refined on the basis of single crystal diffraction data. A phase transition from rhombohedral to cubic at approx. 142 °C was found by measuring the birefringence as a function of temperature, and confirmed by the refined crystal structures",

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language = "English",

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pages = "748--755",

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T1 - Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]

AU - Göbel, Ole

AU - ten Elshof, Johan E.

AU - Schreurs, A.M.M.

PY - 2011

Y1 - 2011

N2 - The crystal structure of (TMA)2[TiF6] between –173 °C and 180 °C was refined on the basis of single crystal diffraction data. A phase transition from rhombohedral to cubic at approx. 142 °C was found by measuring the birefringence as a function of temperature, and confirmed by the refined crystal structures

AB - The crystal structure of (TMA)2[TiF6] between –173 °C and 180 °C was refined on the basis of single crystal diffraction data. A phase transition from rhombohedral to cubic at approx. 142 °C was found by measuring the birefringence as a function of temperature, and confirmed by the refined crystal structures

KW - METIS-280145

U2 - 10.1524/zkri.2011.1401

DO - 10.1524/zkri.2011.1401

M3 - Article

SN - 0044-2968

VL - 226

SP - 748

EP - 755

JO - Zeitschrift für Kristallographie

JF - Zeitschrift für Kristallographie

IS - 9

ER -

Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]

Abstract

Keywords

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