The adsorption and decomposition of carbon monoxide on Ni(100) and the oxidation of the surface carbide by oxygen

Enrico G. Keim; F. Labohm; O.L.J. Gijzeman; G.A. Bootsma; J.W. Geus

doi:10.1016/0039-6028(81)90333-2

The adsorption and decomposition of carbon monoxide on Ni(100) and the oxidation of the surface carbide by oxygen

Enrico G. Keim
, F. Labohm
, O.L.J. Gijzeman
, G.A. Bootsma
, J.W. Geus

University of Twente

Research output: Contribution to journal › Article › Academic

33 Citations (Scopus)

293 Downloads (Pure)

Abstract

The interaction of carbon monoxide with Ni(100) has been studied by ellipsometry and Auger electron spectroscopy. Bombardment by electrons of a relatively high energy (2500 eV) leads to the disproportionation of the adsorbed CO (2 COad → Cad + CO2g ). The rate of oxidation of this surface carbide is , where hc is the carbon 272 eV Auger peak height, n=0.5 and the apparent activation energy Eact =13.3 kcal/mole. This relation is valid at 200–400°C and at oxygen pressures of 5 × 10−9−8 × 10−7 Torr.

Original language	English
Pages (from-to)	52-62
Journal	Surface science
Volume	112
Issue number	1-2
DOIs	https://doi.org/10.1016/0039-6028(81)90333-2
Publication status	Published - 1981

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title = "The adsorption and decomposition of carbon monoxide on Ni(100) and the oxidation of the surface carbide by oxygen",

abstract = "The interaction of carbon monoxide with Ni(100) has been studied by ellipsometry and Auger electron spectroscopy. Bombardment by electrons of a relatively high energy (2500 eV) leads to the disproportionation of the adsorbed CO (2 COad → Cad + CO2g ). The rate of oxidation of this surface carbide is , where hc is the carbon 272 eV Auger peak height, n=0.5 and the apparent activation energy Eact =13.3 kcal/mole. This relation is valid at 200–400°C and at oxygen pressures of 5 × 10−9−8 × 10−7 Torr.",

author = "Keim, \{Enrico G.\} and F. Labohm and O.L.J. Gijzeman and G.A. Bootsma and J.W. Geus",

year = "1981",

doi = "10.1016/0039-6028(81)90333-2",

language = "English",

volume = "112",

pages = "52--62",

journal = "Surface science",

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TY - JOUR

T1 - The adsorption and decomposition of carbon monoxide on Ni(100) and the oxidation of the surface carbide by oxygen

AU - Keim, Enrico G.

AU - Labohm, F.

AU - Gijzeman, O.L.J.

AU - Bootsma, G.A.

AU - Geus, J.W.

PY - 1981

Y1 - 1981

N2 - The interaction of carbon monoxide with Ni(100) has been studied by ellipsometry and Auger electron spectroscopy. Bombardment by electrons of a relatively high energy (2500 eV) leads to the disproportionation of the adsorbed CO (2 COad → Cad + CO2g ). The rate of oxidation of this surface carbide is , where hc is the carbon 272 eV Auger peak height, n=0.5 and the apparent activation energy Eact =13.3 kcal/mole. This relation is valid at 200–400°C and at oxygen pressures of 5 × 10−9−8 × 10−7 Torr.

AB - The interaction of carbon monoxide with Ni(100) has been studied by ellipsometry and Auger electron spectroscopy. Bombardment by electrons of a relatively high energy (2500 eV) leads to the disproportionation of the adsorbed CO (2 COad → Cad + CO2g ). The rate of oxidation of this surface carbide is , where hc is the carbon 272 eV Auger peak height, n=0.5 and the apparent activation energy Eact =13.3 kcal/mole. This relation is valid at 200–400°C and at oxygen pressures of 5 × 10−9−8 × 10−7 Torr.

U2 - 10.1016/0039-6028(81)90333-2

DO - 10.1016/0039-6028(81)90333-2

M3 - Article

SN - 0039-6028

VL - 112

SP - 52

EP - 62

JO - Surface science

JF - Surface science

IS - 1-2

ER -

The adsorption and decomposition of carbon monoxide on Ni(100) and the oxidation of the surface carbide by oxygen

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