The anodic oxidation of bases in the solvent m-cresol

M. Bos, E.A.M.F. Dahmen

    Research output: Contribution to journalArticleAcademic

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    Abstract

    The oxidation of bases in the solvent m-cresol was investigated by polarography, voltammetry at the rotating platinum disc electrode and by chronopotentiometry. It was shown that the m-cresolate ion is the electroactive species in this reaction. The oxidation is a one-electron process giving a phenoxy radical. This phenoxy radical is converted in a chemical reaction of higher than first order, most likely to the dimer.
    Original languageUndefined
    Pages (from-to)169-176
    JournalAnalytica chimica acta
    Volume72
    Issue number1
    DOIs
    Publication statusPublished - 1974

    Keywords

    • IR-68190

    Cite this

    Bos, M. ; Dahmen, E.A.M.F. / The anodic oxidation of bases in the solvent m-cresol. In: Analytica chimica acta. 1974 ; Vol. 72, No. 1. pp. 169-176.
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    The anodic oxidation of bases in the solvent m-cresol. / Bos, M.; Dahmen, E.A.M.F.

    In: Analytica chimica acta, Vol. 72, No. 1, 1974, p. 169-176.

    Research output: Contribution to journalArticleAcademic

    TY - JOUR

    T1 - The anodic oxidation of bases in the solvent m-cresol

    AU - Bos, M.

    AU - Dahmen, E.A.M.F.

    PY - 1974

    Y1 - 1974

    N2 - The oxidation of bases in the solvent m-cresol was investigated by polarography, voltammetry at the rotating platinum disc electrode and by chronopotentiometry. It was shown that the m-cresolate ion is the electroactive species in this reaction. The oxidation is a one-electron process giving a phenoxy radical. This phenoxy radical is converted in a chemical reaction of higher than first order, most likely to the dimer.

    AB - The oxidation of bases in the solvent m-cresol was investigated by polarography, voltammetry at the rotating platinum disc electrode and by chronopotentiometry. It was shown that the m-cresolate ion is the electroactive species in this reaction. The oxidation is a one-electron process giving a phenoxy radical. This phenoxy radical is converted in a chemical reaction of higher than first order, most likely to the dimer.

    KW - IR-68190

    U2 - 10.1016/S0003-2670(01)82960-3

    DO - 10.1016/S0003-2670(01)82960-3

    M3 - Article

    VL - 72

    SP - 169

    EP - 176

    JO - Analytica chimica acta

    JF - Analytica chimica acta

    SN - 0003-2670

    IS - 1

    ER -