Abstract
The hydrolysis of 4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid (DPPDA) esters is induced by lanthanide(III) ions. As the related 2,6-pyridinedicarboxylic acid esters are not cleaved, the effect is traced7 back on improved complexation of the lanthanides by the DPPDA esters. Time-resolved fluorescence spectroscopic and electrospray mass spectrometric investigations on the esters provide information on the progress of the reactions.
Original language | Undefined |
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Pages | - |
DOIs | |
Publication status | Published - 2009 |
Event | Research Workshop, University of Wisconsin - Madison Duration: 1 Jan 1900 → … |
Conference
Conference | Research Workshop, University of Wisconsin |
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City | Madison |
Period | 1/01/00 → … |
Keywords
- Lanthanide complexes
- Electrospray mass spectrometry
- Luminescence
- Phenanthroline
- METIS-256878
- Catalysis
- IR-79832