The determination of major and some minor constituents in lead zirconate-titanate compositions by x-ray fluorescence and atomic absorption spectrometry

J.H.H.G. van Willigen, H. Kruidhof, E.A.M.F. Dahmen

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Abstract

An accurate X-ray fluorescence spectrometric method is described for the determination of lead, zirconium and titanium in lead zirconate-titanate ceramics. Careful matching of samples and standards by a borax fusion method resulted in a relative standard deviation of about 0.2% for the major constituents. The determination, after separation, of the unreacted oxide of lead by atomic absorption spectrometry, and of the unreacted oxides of zirconium and titanium by X-ray fluorescence spectrometry is also described. An X-ray fluorescence spectrometric method is proposed for the determination of dope elements (K, La, Sm, Yb) with internal standards (Ca, Ce, Cr, Ni respectively). The magnesium dope is determined by atomic-absorption spectrometry with standard addition.
Original languageUndefined
Pages (from-to)279-287
JournalAnalytica chimica acta
Volume62
Issue number2
DOIs
Publication statusPublished - 1972

Keywords

  • IR-68120

Cite this

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title = "The determination of major and some minor constituents in lead zirconate-titanate compositions by x-ray fluorescence and atomic absorption spectrometry",
abstract = "An accurate X-ray fluorescence spectrometric method is described for the determination of lead, zirconium and titanium in lead zirconate-titanate ceramics. Careful matching of samples and standards by a borax fusion method resulted in a relative standard deviation of about 0.2{\%} for the major constituents. The determination, after separation, of the unreacted oxide of lead by atomic absorption spectrometry, and of the unreacted oxides of zirconium and titanium by X-ray fluorescence spectrometry is also described. An X-ray fluorescence spectrometric method is proposed for the determination of dope elements (K, La, Sm, Yb) with internal standards (Ca, Ce, Cr, Ni respectively). The magnesium dope is determined by atomic-absorption spectrometry with standard addition.",
keywords = "IR-68120",
author = "{van Willigen}, J.H.H.G. and H. Kruidhof and E.A.M.F. Dahmen",
year = "1972",
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language = "Undefined",
volume = "62",
pages = "279--287",
journal = "Analytica chimica acta",
issn = "0003-2670",
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}

The determination of major and some minor constituents in lead zirconate-titanate compositions by x-ray fluorescence and atomic absorption spectrometry. / van Willigen, J.H.H.G.; Kruidhof, H.; Dahmen, E.A.M.F.

In: Analytica chimica acta, Vol. 62, No. 2, 1972, p. 279-287.

Research output: Contribution to journalArticleAcademic

TY - JOUR

T1 - The determination of major and some minor constituents in lead zirconate-titanate compositions by x-ray fluorescence and atomic absorption spectrometry

AU - van Willigen, J.H.H.G.

AU - Kruidhof, H.

AU - Dahmen, E.A.M.F.

PY - 1972

Y1 - 1972

N2 - An accurate X-ray fluorescence spectrometric method is described for the determination of lead, zirconium and titanium in lead zirconate-titanate ceramics. Careful matching of samples and standards by a borax fusion method resulted in a relative standard deviation of about 0.2% for the major constituents. The determination, after separation, of the unreacted oxide of lead by atomic absorption spectrometry, and of the unreacted oxides of zirconium and titanium by X-ray fluorescence spectrometry is also described. An X-ray fluorescence spectrometric method is proposed for the determination of dope elements (K, La, Sm, Yb) with internal standards (Ca, Ce, Cr, Ni respectively). The magnesium dope is determined by atomic-absorption spectrometry with standard addition.

AB - An accurate X-ray fluorescence spectrometric method is described for the determination of lead, zirconium and titanium in lead zirconate-titanate ceramics. Careful matching of samples and standards by a borax fusion method resulted in a relative standard deviation of about 0.2% for the major constituents. The determination, after separation, of the unreacted oxide of lead by atomic absorption spectrometry, and of the unreacted oxides of zirconium and titanium by X-ray fluorescence spectrometry is also described. An X-ray fluorescence spectrometric method is proposed for the determination of dope elements (K, La, Sm, Yb) with internal standards (Ca, Ce, Cr, Ni respectively). The magnesium dope is determined by atomic-absorption spectrometry with standard addition.

KW - IR-68120

U2 - 10.1016/0003-2670(72)80034-5

DO - 10.1016/0003-2670(72)80034-5

M3 - Article

VL - 62

SP - 279

EP - 287

JO - Analytica chimica acta

JF - Analytica chimica acta

SN - 0003-2670

IS - 2

ER -