The determination of solubility parameters of solvents and polymers by means of correlations with other physical quantities

D.M. Koenhen, C.A. Smolders

Research output: Contribution to journalArticleAcademic

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Abstract

Correlations of solvent solubility parameters with molar attraction constants and with properties like surface tension, dipole moment, and index of refraction have been explored. From relations found to be valid for solvents, it is possible to calculate the solubility parameters for polymers. A relation between the dispersion contribution to the surface energy of polymers (a measurable quantity) and the dispersion solubility parameter of polymers has been found which is similar to a relation established for low molecular weight substances.
Original languageUndefined
Pages (from-to)1163-1179
JournalJournal of applied polymer science
Volume19
Issue number4
DOIs
Publication statusPublished - 1975

Keywords

  • IR-70803

Cite this

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abstract = "Correlations of solvent solubility parameters with molar attraction constants and with properties like surface tension, dipole moment, and index of refraction have been explored. From relations found to be valid for solvents, it is possible to calculate the solubility parameters for polymers. A relation between the dispersion contribution to the surface energy of polymers (a measurable quantity) and the dispersion solubility parameter of polymers has been found which is similar to a relation established for low molecular weight substances.",
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journal = "Journal of applied polymer science",
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The determination of solubility parameters of solvents and polymers by means of correlations with other physical quantities. / Koenhen, D.M.; Smolders, C.A.

In: Journal of applied polymer science, Vol. 19, No. 4, 1975, p. 1163-1179.

Research output: Contribution to journalArticleAcademic

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T1 - The determination of solubility parameters of solvents and polymers by means of correlations with other physical quantities

AU - Koenhen, D.M.

AU - Smolders, C.A.

PY - 1975

Y1 - 1975

N2 - Correlations of solvent solubility parameters with molar attraction constants and with properties like surface tension, dipole moment, and index of refraction have been explored. From relations found to be valid for solvents, it is possible to calculate the solubility parameters for polymers. A relation between the dispersion contribution to the surface energy of polymers (a measurable quantity) and the dispersion solubility parameter of polymers has been found which is similar to a relation established for low molecular weight substances.

AB - Correlations of solvent solubility parameters with molar attraction constants and with properties like surface tension, dipole moment, and index of refraction have been explored. From relations found to be valid for solvents, it is possible to calculate the solubility parameters for polymers. A relation between the dispersion contribution to the surface energy of polymers (a measurable quantity) and the dispersion solubility parameter of polymers has been found which is similar to a relation established for low molecular weight substances.

KW - IR-70803

U2 - 10.1002/app.1975.070190423

DO - 10.1002/app.1975.070190423

M3 - Article

VL - 19

SP - 1163

EP - 1179

JO - Journal of applied polymer science

JF - Journal of applied polymer science

SN - 0021-8995

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ER -