The nitric acid oxidation of 2-octanol. A model reaction for multiple heterogeneous liquid-liquid reactions

B.A.A. van Woezik; K.R. Westerterp

doi:10.1016/S0255-2701(00)00099-4

The nitric acid oxidation of 2-octanol. A model reaction for multiple heterogeneous liquid-liquid reactions

B.A.A. van Woezik, K.R. Westerterp

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Abstract

The oxidation of 2-octanol with nitric acid has been selected as a model reaction for a heterogeneous liquid–liquid reaction with an undesired side reaction. 2-Octanol is first oxidized to 2-octanone, which can be further oxidized to carboxylic acids. An extensive experimental program has been followed using heat flow calorimetry supported by chemical analysis. A series of oxidation experiments has been carried out to study the influence of different initial and operating conditions such as temperature, stirring speed and feed rate. In parallel a semi-empirical model has been developed to describe the conversion rates.

Original language	Undefined
Pages (from-to)	521-537
Number of pages	17
Journal	Chemical engineering and processing : process intensification
Volume	39
Issue number	6
DOIs	https://doi.org/10.1016/S0255-2701(00)00099-4
Publication status	Published - 2000

Keywords

METIS-106094
IR-74312
Nitric acid oxidations
Slow liquid–liquid reaction
Hammett's acidity function
Complex kinetics

Access to Document

10.1016/S0255-2701(00)00099-4

Cite this

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title = "The nitric acid oxidation of 2-octanol. A model reaction for multiple heterogeneous liquid-liquid reactions",

abstract = "The oxidation of 2-octanol with nitric acid has been selected as a model reaction for a heterogeneous liquid–liquid reaction with an undesired side reaction. 2-Octanol is first oxidized to 2-octanone, which can be further oxidized to carboxylic acids. An extensive experimental program has been followed using heat flow calorimetry supported by chemical analysis. A series of oxidation experiments has been carried out to study the influence of different initial and operating conditions such as temperature, stirring speed and feed rate. In parallel a semi-empirical model has been developed to describe the conversion rates.",

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T1 - The nitric acid oxidation of 2-octanol. A model reaction for multiple heterogeneous liquid-liquid reactions

AU - van Woezik, B.A.A.

AU - Westerterp, K.R.

PY - 2000

Y1 - 2000

N2 - The oxidation of 2-octanol with nitric acid has been selected as a model reaction for a heterogeneous liquid–liquid reaction with an undesired side reaction. 2-Octanol is first oxidized to 2-octanone, which can be further oxidized to carboxylic acids. An extensive experimental program has been followed using heat flow calorimetry supported by chemical analysis. A series of oxidation experiments has been carried out to study the influence of different initial and operating conditions such as temperature, stirring speed and feed rate. In parallel a semi-empirical model has been developed to describe the conversion rates.

AB - The oxidation of 2-octanol with nitric acid has been selected as a model reaction for a heterogeneous liquid–liquid reaction with an undesired side reaction. 2-Octanol is first oxidized to 2-octanone, which can be further oxidized to carboxylic acids. An extensive experimental program has been followed using heat flow calorimetry supported by chemical analysis. A series of oxidation experiments has been carried out to study the influence of different initial and operating conditions such as temperature, stirring speed and feed rate. In parallel a semi-empirical model has been developed to describe the conversion rates.

KW - METIS-106094

KW - IR-74312

KW - Nitric acid oxidations

KW - Slow liquid–liquid reaction

KW - Hammett's acidity function

KW - Complex kinetics

U2 - 10.1016/S0255-2701(00)00099-4

DO - 10.1016/S0255-2701(00)00099-4

M3 - Article

SN - 0255-2701

VL - 39

SP - 521

EP - 537

JO - Chemical engineering and processing : process intensification

JF - Chemical engineering and processing : process intensification

IS - 6

ER -