TY - JOUR
T1 - The Organization of Two Soft (Cu2Ө, Ni2Ө) Metal Centers in Heterotrinuclear Complexes of a Macrocyclic Ligand by Cocomplexation with Ba2Ө
AU - van Veggel, F.C.J.M.
AU - Bos, M.
AU - Harkema, Sybolt
AU - Verboom, Willem
AU - Reinhoudt, David
PY - 1989
Y1 - 1989
N2 - The short distances between the two transitionmetal centers in the trinuclear complexes 3 are caused by cocomplexation of Ba2Ө: Cu2Ө:...Cu2Ө 3.50, Ni2Ө ...Ni2Ө 3.42 Å. The macrocyclic ligand is formed as the complex 2 from o-phenylenediamine and 1 in the presence of Ba2Ө. Complexes 3, in turn, are obtained by treatment of 2 with copper or nickel acetate.
AB - The short distances between the two transitionmetal centers in the trinuclear complexes 3 are caused by cocomplexation of Ba2Ө: Cu2Ө:...Cu2Ө 3.50, Ni2Ө ...Ni2Ө 3.42 Å. The macrocyclic ligand is formed as the complex 2 from o-phenylenediamine and 1 in the presence of Ba2Ө. Complexes 3, in turn, are obtained by treatment of 2 with copper or nickel acetate.
KW - IR-70887
U2 - 10.1002/anie.198907461
DO - 10.1002/anie.198907461
M3 - Article
SN - 0570-0833
VL - 28
SP - 746
EP - 748
JO - Angewandte Chemie, International Edition in English
JF - Angewandte Chemie, International Edition in English
IS - 6
ER -