The Organization of Two Soft (Cu2Ө, Ni2Ө) Metal Centers in Heterotrinuclear Complexes of a Macrocyclic Ligand by Cocomplexation with Ba2Ө

F.C.J.M. van Veggel; M. Bos; Sybolt Harkema; Willem Verboom; David Reinhoudt

doi:10.1002/anie.198907461

The Organization of Two Soft (Cu2Ө, Ni2Ө) Metal Centers in Heterotrinuclear Complexes of a Macrocyclic Ligand by Cocomplexation with Ba2Ө

F.C.J.M. van Veggel
, M. Bos
, Sybolt Harkema
, Willem Verboom
, David Reinhoudt

Research output: Contribution to journal › Article › Academic

52 Citations (Scopus)

201 Downloads (Pure)

Abstract

The short distances between the two transitionmetal centers in the trinuclear complexes 3 are caused by cocomplexation of Ba2Ө: Cu2Ө:...Cu2Ө 3.50, Ni2Ө ...Ni2Ө 3.42 Å. The macrocyclic ligand is formed as the complex 2 from o-phenylenediamine and 1 in the presence of Ba2Ө. Complexes 3, in turn, are obtained by treatment of 2 with copper or nickel acetate.

Original language	Undefined
Pages (from-to)	746-748
Journal	Angewandte Chemie, International Edition in English
Volume	28
Issue number	6
DOIs	https://doi.org/10.1002/anie.198907461
Publication status	Published - 1989

Keywords

IR-70887

Access to Document

10.1002/anie.198907461

Veggel89organization

Cite this

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title = "The Organization of Two Soft (Cu2Ө, Ni2Ө) Metal Centers in Heterotrinuclear Complexes of a Macrocyclic Ligand by Cocomplexation with Ba2Ө",

abstract = "The short distances between the two transitionmetal centers in the trinuclear complexes 3 are caused by cocomplexation of Ba2Ө: Cu2Ө:...Cu2Ө 3.50, Ni2Ө ...Ni2Ө 3.42 {\AA}. The macrocyclic ligand is formed as the complex 2 from o-phenylenediamine and 1 in the presence of Ba2Ө. Complexes 3, in turn, are obtained by treatment of 2 with copper or nickel acetate.",

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year = "1989",

doi = "10.1002/anie.198907461",

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volume = "28",

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journal = "Angewandte Chemie, International Edition in English",

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T1 - The Organization of Two Soft (Cu2Ө, Ni2Ө) Metal Centers in Heterotrinuclear Complexes of a Macrocyclic Ligand by Cocomplexation with Ba2Ө

AU - van Veggel, F.C.J.M.

AU - Bos, M.

AU - Harkema, Sybolt

AU - Verboom, Willem

AU - Reinhoudt, David

PY - 1989

Y1 - 1989

N2 - The short distances between the two transitionmetal centers in the trinuclear complexes 3 are caused by cocomplexation of Ba2Ө: Cu2Ө:...Cu2Ө 3.50, Ni2Ө ...Ni2Ө 3.42 Å. The macrocyclic ligand is formed as the complex 2 from o-phenylenediamine and 1 in the presence of Ba2Ө. Complexes 3, in turn, are obtained by treatment of 2 with copper or nickel acetate.

AB - The short distances between the two transitionmetal centers in the trinuclear complexes 3 are caused by cocomplexation of Ba2Ө: Cu2Ө:...Cu2Ө 3.50, Ni2Ө ...Ni2Ө 3.42 Å. The macrocyclic ligand is formed as the complex 2 from o-phenylenediamine and 1 in the presence of Ba2Ө. Complexes 3, in turn, are obtained by treatment of 2 with copper or nickel acetate.

KW - IR-70887

U2 - 10.1002/anie.198907461

DO - 10.1002/anie.198907461

M3 - Article

SN - 0570-0833

VL - 28

SP - 746

EP - 748

JO - Angewandte Chemie, International Edition in English

JF - Angewandte Chemie, International Edition in English

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