The organocatalytic ring-opening polymerization of N -tosyl aziridines by an N-heterocyclic carbene

Camille Bakkali-Hassani; Elisabeth Rieger; Joan Vignolle; Frederik R. Wurm; Stéphane Carlotti; Daniel Taton

doi:10.1039/c6cc04323b

The organocatalytic ring-opening polymerization of N -tosyl aziridines by an N-heterocyclic carbene

Camille Bakkali-Hassani, Elisabeth Rieger, Joan Vignolle, Frederik R. Wurm^*, Stéphane Carlotti^*, Daniel Taton

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The ring-opening polymerization of N-tosyl aziridines, in the presence of 1,3-bis(isopropyl)-4,5(dimethyl)imidazol-2-ylidene as an organocatalyst and an N-tosyl secondary amine as initiator mimicking the growing chain, provides the first metal-free route to well defined poly(aziridine)s (PAz) and related PAz-based block copolymers.

Original language	English
Pages (from-to)	9719-9722
Number of pages	4
Journal	Chemical communications
Volume	52
Issue number	62
DOIs	https://doi.org/10.1039/c6cc04323b
Publication status	Published - 1 Jan 2016
Externally published	Yes

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Bakkali-hassani-2016-The-organocatalytic-ring-opening-poFinal published version, 1.75 MBLicence: CC BY

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AU - Bakkali-Hassani, Camille

AU - Rieger, Elisabeth

AU - Vignolle, Joan

AU - Wurm, Frederik R.

AU - Carlotti, Stéphane

AU - Taton, Daniel

PY - 2016/1/1

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AB - The ring-opening polymerization of N-tosyl aziridines, in the presence of 1,3-bis(isopropyl)-4,5(dimethyl)imidazol-2-ylidene as an organocatalyst and an N-tosyl secondary amine as initiator mimicking the growing chain, provides the first metal-free route to well defined poly(aziridine)s (PAz) and related PAz-based block copolymers.

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DO - 10.1039/c6cc04323b

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ER -

The organocatalytic ring-opening polymerization of N -tosyl aziridines by an N-heterocyclic carbene

Abstract

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