The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites

H.H. Le; S. Abhijeet; S. Ilish; J. Klehm; S. Henning; M. Beiner; S.S. Sarkawi; W. Dierkes; A. Das; D. Fischer; K.-W. Stöckelhuber; S. Wiessner; S.P. Khatiwada; R. Adhikari; T. Pham; G. Heinrich; H.-J. Radusch

doi:10.1016/j.polymer.2014.07.043

The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites

H.H. Le, S. Abhijeet, S. Ilish, J. Klehm, S. Henning, M. Beiner, S.S. Sarkawi, W. Dierkes, A. Das, D. Fischer, K.-W. Stöckelhuber, S. Wiessner, S.P. Khatiwada, R. Adhikari, T. Pham, G. Heinrich, H.-J. Radusch

Research output: Contribution to journal › Article › Academic › peer-review

53 Citations (Scopus)

Abstract

The aim of the present work is to evidence the role of the linked phospholipids of natural rubber (NR) in the rubber-carbon nanotube (CNT) interactions in rubber composites. Three rubbers namely NR, deproteinized NR (DPNR) and a synthetic rubber isoprene (IR) were used as matrix for CNTs. The selective wetting of CNTs in miscible NR/IR and DPNR/IR blends was investigated by means of the modified wetting concept based on Fourier transformed infrared (FTIR) analysis of the rubber-filler gel of blends. It revealed that the surface of CNTs is entirely wetted by NR or DPNR molecules, respectively, but not by IR. This result emphasizes that proteins do not influence the affinity between NR and CNTs, while the linked phospholipids interact with CNT surface through cation-π linkage. This linkage acts as anchor point supporting NR molecules to wet CNT surface effectively. The modified wetting concept can be used for characterization of selective wetting of different fillers in blends consisting of miscible rubber components.

Original language	English
Pages (from-to)	4738-4747
Number of pages	10
Journal	Polymer
Volume	55
Issue number	18
DOIs	https://doi.org/10.1016/j.polymer.2014.07.043
Publication status	Published - 1 Aug 2014

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Le, H. H., Abhijeet, S., Ilish, S., Klehm, J., Henning, S., Beiner, M., Sarkawi, S. S., Dierkes, W., Das, A., Fischer, D., Stöckelhuber, K-W., Wiessner, S., Khatiwada, S. P., Adhikari, R., Pham, T., Heinrich, G., & Radusch, H-J. (2014). The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites. Polymer, 55(18), 4738-4747. https://doi.org/10.1016/j.polymer.2014.07.043

Le, H.H. ; Abhijeet, S. ; Ilish, S. ; Klehm, J. ; Henning, S. ; Beiner, M. ; Sarkawi, S.S. ; Dierkes, W. ; Das, A. ; Fischer, D. ; Stöckelhuber, K.-W. ; Wiessner, S. ; Khatiwada, S.P. ; Adhikari, R. ; Pham, T. ; Heinrich, G. ; Radusch, H.-J. / The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites. In: Polymer. 2014 ; Vol. 55, No. 18. pp. 4738-4747.

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title = "The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites",

abstract = "The aim of the present work is to evidence the role of the linked phospholipids of natural rubber (NR) in the rubber-carbon nanotube (CNT) interactions in rubber composites. Three rubbers namely NR, deproteinized NR (DPNR) and a synthetic rubber isoprene (IR) were used as matrix for CNTs. The selective wetting of CNTs in miscible NR/IR and DPNR/IR blends was investigated by means of the modified wetting concept based on Fourier transformed infrared (FTIR) analysis of the rubber-filler gel of blends. It revealed that the surface of CNTs is entirely wetted by NR or DPNR molecules, respectively, but not by IR. This result emphasizes that proteins do not influence the affinity between NR and CNTs, while the linked phospholipids interact with CNT surface through cation-π linkage. This linkage acts as anchor point supporting NR molecules to wet CNT surface effectively. The modified wetting concept can be used for characterization of selective wetting of different fillers in blends consisting of miscible rubber components.",

author = "H.H. Le and S. Abhijeet and S. Ilish and J. Klehm and S. Henning and M. Beiner and S.S. Sarkawi and W. Dierkes and A. Das and D. Fischer and K.-W. St{\"o}ckelhuber and S. Wiessner and S.P. Khatiwada and R. Adhikari and T. Pham and G. Heinrich and H.-J. Radusch",

year = "2014",

month = aug,

day = "1",

doi = "10.1016/j.polymer.2014.07.043",

language = "English",

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Le, HH, Abhijeet, S, Ilish, S, Klehm, J, Henning, S, Beiner, M, Sarkawi, SS, Dierkes, W, Das, A, Fischer, D, Stöckelhuber, K-W, Wiessner, S, Khatiwada, SP, Adhikari, R, Pham, T, Heinrich, G & Radusch, H-J 2014, 'The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites', Polymer, vol. 55, no. 18, pp. 4738-4747. https://doi.org/10.1016/j.polymer.2014.07.043

The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites. / Le, H.H.; Abhijeet, S.; Ilish, S.; Klehm, J.; Henning, S.; Beiner, M.; Sarkawi, S.S.; Dierkes, W.; Das, A.; Fischer, D.; Stöckelhuber, K.-W.; Wiessner, S.; Khatiwada, S.P.; Adhikari, R.; Pham, T.; Heinrich, G.; Radusch, H.-J.

In: Polymer, Vol. 55, No. 18, 01.08.2014, p. 4738-4747.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites

AU - Le, H.H.

AU - Abhijeet, S.

AU - Ilish, S.

AU - Klehm, J.

AU - Henning, S.

AU - Beiner, M.

AU - Sarkawi, S.S.

AU - Dierkes, W.

AU - Das, A.

AU - Fischer, D.

AU - Stöckelhuber, K.-W.

AU - Wiessner, S.

AU - Khatiwada, S.P.

AU - Adhikari, R.

AU - Pham, T.

AU - Heinrich, G.

AU - Radusch, H.-J.

PY - 2014/8/1

Y1 - 2014/8/1

N2 - The aim of the present work is to evidence the role of the linked phospholipids of natural rubber (NR) in the rubber-carbon nanotube (CNT) interactions in rubber composites. Three rubbers namely NR, deproteinized NR (DPNR) and a synthetic rubber isoprene (IR) were used as matrix for CNTs. The selective wetting of CNTs in miscible NR/IR and DPNR/IR blends was investigated by means of the modified wetting concept based on Fourier transformed infrared (FTIR) analysis of the rubber-filler gel of blends. It revealed that the surface of CNTs is entirely wetted by NR or DPNR molecules, respectively, but not by IR. This result emphasizes that proteins do not influence the affinity between NR and CNTs, while the linked phospholipids interact with CNT surface through cation-π linkage. This linkage acts as anchor point supporting NR molecules to wet CNT surface effectively. The modified wetting concept can be used for characterization of selective wetting of different fillers in blends consisting of miscible rubber components.

AB - The aim of the present work is to evidence the role of the linked phospholipids of natural rubber (NR) in the rubber-carbon nanotube (CNT) interactions in rubber composites. Three rubbers namely NR, deproteinized NR (DPNR) and a synthetic rubber isoprene (IR) were used as matrix for CNTs. The selective wetting of CNTs in miscible NR/IR and DPNR/IR blends was investigated by means of the modified wetting concept based on Fourier transformed infrared (FTIR) analysis of the rubber-filler gel of blends. It revealed that the surface of CNTs is entirely wetted by NR or DPNR molecules, respectively, but not by IR. This result emphasizes that proteins do not influence the affinity between NR and CNTs, while the linked phospholipids interact with CNT surface through cation-π linkage. This linkage acts as anchor point supporting NR molecules to wet CNT surface effectively. The modified wetting concept can be used for characterization of selective wetting of different fillers in blends consisting of miscible rubber components.

U2 - 10.1016/j.polymer.2014.07.043

DO - 10.1016/j.polymer.2014.07.043

M3 - Article

VL - 55

SP - 4738

EP - 4747

JO - Polymer

JF - Polymer

SN - 0032-3861

IS - 18

ER -

The role of linked phospholipids in the rubber-filler interaction in carbon nanotube (CNT) filler natural rubber (NR) composites

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