The Role of Solvent in Carbon Quantum Dot Synthesis on the Performance of MoS2 Nanosheet/Carbon Quantum Dot Heterostructures as Electrocatalysts for the Hydrogen Evolution Reaction

Fani Rahayu Hidayah Rayanisaputri, Didik Aryanto, Lazar Bijelić, Arturo Susarrey-Arce, Francisco Ruiz-Zepeda, Ferry Anggoro Ardy Nugroho, Vivi Fauzia

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

This study investigates the effect of different solvents used in the synthesis of carbon quantum dots (CQDs) on the electrocatalytic performance of MoS 2/CQD heterostructures for the hydrogen evolution reaction (HER). While previous research focused on CQDs synthesized with deionized water, little attention has been given to the influence of other solvents on CQD electrocatalytic behavior. To address this, we synthesized MoS 2 on 3D carbon cloths via a hydrothermal method and subsequently incorporated CQDs synthesized using deionized water, glycerol, and dimethylformamide (DMF). The choice of solvent significantly impacts their morphology, crystallinity, surface, and electrochemical properties. In particular, MoS 2 nanosheets became smaller with increased disordered structures and defect sites, particularly sulfur vacancies. Among the heterostructures, MoS 2/CQDs-Glycerol showed superior performance, with an onset overpotential of 130 mV and Tafel slope of 53 mV/dec at 10 mA/cm 2, outperforming MoS 2/CQDs-DI (149 mV, 68 mV/dec) and MoS 2/CQDs-DMF (185 mV, 106 mV/dec). The enhanced performance of MoS 2/CQDs-Glycerol is attributed to its larger active surface area (C dl of 228.7 mF/cm 2) and lower charge transfer resistance (R ct of 2.25 Ω), which may be due to the formation of more Mo-S edges on the vertical plane, serving as active sites. This study demonstrates that glycerol is the most effective solvent in CQD synthesis for enhancing HER performance by improving the morphology, surface properties, and charge transfer.

Original languageEnglish
Pages (from-to)1479-1489
Number of pages11
JournalACS Applied Nano Materials
Volume8
Issue number3
Early online date10 Jan 2025
DOIs
Publication statusPublished - 24 Jan 2025

Keywords

  • 2025 OA procedure

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