The role of tin in Li/Sn/MgO catalysts for the oxidative coupling of methaneThe role of Li/Sn/MgO catalysis for the oxidative coupling of methane

A.N.J. van Keulen; G.C. Hoogendam; K. Seshan; J.G. van Ommen; J.R.H. Ross

doi:10.1039/C39920001546

The role of tin in Li/Sn/MgO catalysts for the oxidative coupling of methaneThe role of Li/Sn/MgO catalysis for the oxidative coupling of methane

A.N.J. van Keulen
, G.C. Hoogendam
, K. Seshan
, J.G. van Ommen
, J.R.H. Ross

Catalytic Processes and Materials

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The addition of SnO₂ to the Li/MgO catalyst system has been found to stabilize its catalytic activity for the oxidative coupling of methane, and, when a large amount of SnO₂ is added, a new phase, Li₂Mg₃SnO₆ is identified; pure Li₂Mg₃SnO₆ is also an active and selective catalyst for the oxidative coupling of methane, and in contrast with Li/MgO, it retains lithium under reaction conditions, thereby suppressing deactivation.

Original language	English
Pages (from-to)	1546-1547
Number of pages	2
Journal	Journal of the Chemical Society. Chemical communications
Volume	1992
Issue number	21
DOIs	https://doi.org/10.1039/C39920001546
Publication status	Published - 1992

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title = "The role of tin in Li/Sn/MgO catalysts for the oxidative coupling of methaneThe role of Li/Sn/MgO catalysis for the oxidative coupling of methane",

abstract = "The addition of SnO2 to the Li/MgO catalyst system has been found to stabilize its catalytic activity for the oxidative coupling of methane, and, when a large amount of SnO2 is added, a new phase, Li2Mg3SnO6 is identified; pure Li2Mg3SnO6 is also an active and selective catalyst for the oxidative coupling of methane, and in contrast with Li/MgO, it retains lithium under reaction conditions, thereby suppressing deactivation.",

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journal = "Journal of the Chemical Society. Chemical communications",

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The role of tin in Li/Sn/MgO catalysts for the oxidative coupling of methaneThe role of Li/Sn/MgO catalysis for the oxidative coupling of methane. / van Keulen, A.N.J.; Hoogendam, G.C.; Seshan, K. et al.
In: Journal of the Chemical Society. Chemical communications, Vol. 1992, No. 21, 1992, p. 1546-1547.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - The role of tin in Li/Sn/MgO catalysts for the oxidative coupling of methaneThe role of Li/Sn/MgO catalysis for the oxidative coupling of methane

AU - van Keulen, A.N.J.

AU - Hoogendam, G.C.

AU - Seshan, K.

AU - van Ommen, J.G.

AU - Ross, J.R.H.

PY - 1992

Y1 - 1992

N2 - The addition of SnO2 to the Li/MgO catalyst system has been found to stabilize its catalytic activity for the oxidative coupling of methane, and, when a large amount of SnO2 is added, a new phase, Li2Mg3SnO6 is identified; pure Li2Mg3SnO6 is also an active and selective catalyst for the oxidative coupling of methane, and in contrast with Li/MgO, it retains lithium under reaction conditions, thereby suppressing deactivation.

AB - The addition of SnO2 to the Li/MgO catalyst system has been found to stabilize its catalytic activity for the oxidative coupling of methane, and, when a large amount of SnO2 is added, a new phase, Li2Mg3SnO6 is identified; pure Li2Mg3SnO6 is also an active and selective catalyst for the oxidative coupling of methane, and in contrast with Li/MgO, it retains lithium under reaction conditions, thereby suppressing deactivation.

U2 - 10.1039/C39920001546

DO - 10.1039/C39920001546

M3 - Article

SN - 0022-4936

VL - 1992

SP - 1546

EP - 1547

JO - Journal of the Chemical Society. Chemical communications

JF - Journal of the Chemical Society. Chemical communications

IS - 21

ER -

The role of tin in Li/Sn/MgO catalysts for the oxidative coupling of methaneThe role of Li/Sn/MgO catalysis for the oxidative coupling of methane

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