Thermoplastic elastomers based on poly(lactide)-poly(trimethylene carbonate-co-caprolactone)-poly(lactide) triblock copolymers and their stereocomplexes

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Triblock copolymers of poly(l-lactide)–poly(trimethylene carbonate-co-caprolactone)–poly(l-lactide) and poly(d-lactide)–poly(trimethylene carbonate-co-caprolactone)–poly(d-lactide) were prepared by sequential ring-opening polymerizations. These polymers are thermoplastic elastomers (TPEs) with good tensile properties and excellent resistance to creep. In equimolar blends of these enantiomeric copolymers, stereocomplexation between the enantiomeric poly(lactide) segments occurs. Due to the enhanced phase separation, the specimens of stereocomplex have even better resistance to creep than the enantiomeric block copolymers.
Original languageEnglish
Pages (from-to)e29-e31
JournalJournal of controlled release
Issue number2
Publication statusPublished - 2006
Event9th European Symposium on Controlled Drug Delivery, ESCDD 2006 - Noordwijk aan Zee, Netherlands
Duration: 5 Apr 20067 Apr 2006
Conference number: 9


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