Three electrode current voltage measurements on erbia stabilized bismuth oxide with co-pressed gold gauze electrodes

I.C. Vinke, I.C. Vinke, Bernard A. Boukamp, K.J. de Vries, Karel Jan de Vries, Anthonie Burggraaf, A.J. Burggraaf

Research output: Contribution to journalArticleProfessional

6 Citations (Scopus)
59 Downloads (Pure)

Abstract

The polarization behaviour of (Bi2O3)0.75(Er2O3)0.25(BE25) with a co-pressed gold gauze electrode was studied as a function of temperature and oxygen partial pressure in a three electrode cell. The anodic polarization is smaller than the cathodic polarization. The cathodic charge transfer coefficient, αc, is about 0.5 while the anodic one, αa, is about 1.5. The exchange current density shows a (PO2) dependence for partial pressures below 1 atm with an activation enthalpy of ˜126 kJ mol−1. These values compare well with results obtained from 18O exchange experiments. Current densities for the co-pressed gold gauze electrodes are about a factor of 5 to 10 larger than found for the previously reported porous sputtered gold electrodes. Analysis of the electrode impedance shows strong influence of surface diffusion on the electrode reaction, which must take place at the surface of the electrolyte.
Original languageUndefined
Pages (from-to)33-40
Number of pages8
JournalSolid state ionics
Volume58
Issue number1/2
DOIs
Publication statusPublished - 1992

Keywords

  • IR-13571
  • METIS-109479

Cite this

Vinke, I.C. ; Vinke, I.C. ; Boukamp, Bernard A. ; de Vries, K.J. ; de Vries, Karel Jan ; Burggraaf, Anthonie ; Burggraaf, A.J. / Three electrode current voltage measurements on erbia stabilized bismuth oxide with co-pressed gold gauze electrodes. In: Solid state ionics. 1992 ; Vol. 58, No. 1/2. pp. 33-40.
@article{31d2b894f3944ed88e8548cb36bbde87,
title = "Three electrode current voltage measurements on erbia stabilized bismuth oxide with co-pressed gold gauze electrodes",
abstract = "The polarization behaviour of (Bi2O3)0.75(Er2O3)0.25(BE25) with a co-pressed gold gauze electrode was studied as a function of temperature and oxygen partial pressure in a three electrode cell. The anodic polarization is smaller than the cathodic polarization. The cathodic charge transfer coefficient, αc, is about 0.5 while the anodic one, αa, is about 1.5. The exchange current density shows a (PO2) dependence for partial pressures below 1 atm with an activation enthalpy of ˜126 kJ mol−1. These values compare well with results obtained from 18O exchange experiments. Current densities for the co-pressed gold gauze electrodes are about a factor of 5 to 10 larger than found for the previously reported porous sputtered gold electrodes. Analysis of the electrode impedance shows strong influence of surface diffusion on the electrode reaction, which must take place at the surface of the electrolyte.",
keywords = "IR-13571, METIS-109479",
author = "I.C. Vinke and I.C. Vinke and Boukamp, {Bernard A.} and {de Vries}, K.J. and {de Vries}, {Karel Jan} and Anthonie Burggraaf and A.J. Burggraaf",
year = "1992",
doi = "10.1016/0167-2738(92)90007-C",
language = "Undefined",
volume = "58",
pages = "33--40",
journal = "Solid state ionics",
issn = "0167-2738",
publisher = "Elsevier",
number = "1/2",

}

Three electrode current voltage measurements on erbia stabilized bismuth oxide with co-pressed gold gauze electrodes. / Vinke, I.C.; Vinke, I.C.; Boukamp, Bernard A.; de Vries, K.J.; de Vries, Karel Jan; Burggraaf, Anthonie; Burggraaf, A.J.

In: Solid state ionics, Vol. 58, No. 1/2, 1992, p. 33-40.

Research output: Contribution to journalArticleProfessional

TY - JOUR

T1 - Three electrode current voltage measurements on erbia stabilized bismuth oxide with co-pressed gold gauze electrodes

AU - Vinke, I.C.

AU - Vinke, I.C.

AU - Boukamp, Bernard A.

AU - de Vries, K.J.

AU - de Vries, Karel Jan

AU - Burggraaf, Anthonie

AU - Burggraaf, A.J.

PY - 1992

Y1 - 1992

N2 - The polarization behaviour of (Bi2O3)0.75(Er2O3)0.25(BE25) with a co-pressed gold gauze electrode was studied as a function of temperature and oxygen partial pressure in a three electrode cell. The anodic polarization is smaller than the cathodic polarization. The cathodic charge transfer coefficient, αc, is about 0.5 while the anodic one, αa, is about 1.5. The exchange current density shows a (PO2) dependence for partial pressures below 1 atm with an activation enthalpy of ˜126 kJ mol−1. These values compare well with results obtained from 18O exchange experiments. Current densities for the co-pressed gold gauze electrodes are about a factor of 5 to 10 larger than found for the previously reported porous sputtered gold electrodes. Analysis of the electrode impedance shows strong influence of surface diffusion on the electrode reaction, which must take place at the surface of the electrolyte.

AB - The polarization behaviour of (Bi2O3)0.75(Er2O3)0.25(BE25) with a co-pressed gold gauze electrode was studied as a function of temperature and oxygen partial pressure in a three electrode cell. The anodic polarization is smaller than the cathodic polarization. The cathodic charge transfer coefficient, αc, is about 0.5 while the anodic one, αa, is about 1.5. The exchange current density shows a (PO2) dependence for partial pressures below 1 atm with an activation enthalpy of ˜126 kJ mol−1. These values compare well with results obtained from 18O exchange experiments. Current densities for the co-pressed gold gauze electrodes are about a factor of 5 to 10 larger than found for the previously reported porous sputtered gold electrodes. Analysis of the electrode impedance shows strong influence of surface diffusion on the electrode reaction, which must take place at the surface of the electrolyte.

KW - IR-13571

KW - METIS-109479

U2 - 10.1016/0167-2738(92)90007-C

DO - 10.1016/0167-2738(92)90007-C

M3 - Article

VL - 58

SP - 33

EP - 40

JO - Solid state ionics

JF - Solid state ionics

SN - 0167-2738

IS - 1/2

ER -