Time, Space. and Spectrally Resolved Studies on J-Aggregate Interactions in Zeolite L Nanochannels

Michael Busby; Christian Blum; Marc Tibben; Sandra Fibikar; Gion Calzaferri; Vinod Subramaniam; Luisa De Cola; L. de Cola

doi:10.1021/ja801178p

Time, Space. and Spectrally Resolved Studies on J-Aggregate Interactions in Zeolite L Nanochannels

Michael Busby, Christian Blum, Marc Tibben, Sandra Fibikar, Gion Calzaferri, Vinod Subramaniam, Luisa De Cola, L. de Cola

Research output: Contribution to journal › Article › Academic › peer-review

89 Citations (Scopus)

Abstract

Temporally and spectrally resolved confocal microscopy has been used to explore the behavior of pyronine intercalated zeolite L crystals at different loadings. The low pyronine loading of 0.6% exhibits photophysical behavior similar to that of the free molecule in solution, indicating molecules are isolated from each other in the crystal channels. The higher loading of 20% results in a dye gradient along the channel axis, and the presence of an additional red-shifted spectroscopic transition, with shorter lifetimes. The new band is assigned to an inline arrangement of the molecules undergoing a J-aggregate-type coupling, a process so far not observed in subnanometer channels.

Original language	Undefined
Pages (from-to)	-
Journal	Journal of the American Chemical Society
Volume	130
Issue number	33
DOIs	https://doi.org/10.1021/ja801178p
Publication status	Published - 2008

Keywords

METIS-248976
IR-75519

Access to Document

10.1021/ja801178p

Cite this

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abstract = "Temporally and spectrally resolved confocal microscopy has been used to explore the behavior of pyronine intercalated zeolite L crystals at different loadings. The low pyronine loading of 0.6% exhibits photophysical behavior similar to that of the free molecule in solution, indicating molecules are isolated from each other in the crystal channels. The higher loading of 20% results in a dye gradient along the channel axis, and the presence of an additional red-shifted spectroscopic transition, with shorter lifetimes. The new band is assigned to an inline arrangement of the molecules undergoing a J-aggregate-type coupling, a process so far not observed in subnanometer channels.",

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T1 - Time, Space. and Spectrally Resolved Studies on J-Aggregate Interactions in Zeolite L Nanochannels

AU - Busby, Michael

AU - Blum, Christian

AU - Tibben, Marc

AU - Fibikar, Sandra

AU - Calzaferri, Gion

AU - Subramaniam, Vinod

AU - De Cola, Luisa

AU - de Cola, L.

PY - 2008

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N2 - Temporally and spectrally resolved confocal microscopy has been used to explore the behavior of pyronine intercalated zeolite L crystals at different loadings. The low pyronine loading of 0.6% exhibits photophysical behavior similar to that of the free molecule in solution, indicating molecules are isolated from each other in the crystal channels. The higher loading of 20% results in a dye gradient along the channel axis, and the presence of an additional red-shifted spectroscopic transition, with shorter lifetimes. The new band is assigned to an inline arrangement of the molecules undergoing a J-aggregate-type coupling, a process so far not observed in subnanometer channels.

AB - Temporally and spectrally resolved confocal microscopy has been used to explore the behavior of pyronine intercalated zeolite L crystals at different loadings. The low pyronine loading of 0.6% exhibits photophysical behavior similar to that of the free molecule in solution, indicating molecules are isolated from each other in the crystal channels. The higher loading of 20% results in a dye gradient along the channel axis, and the presence of an additional red-shifted spectroscopic transition, with shorter lifetimes. The new band is assigned to an inline arrangement of the molecules undergoing a J-aggregate-type coupling, a process so far not observed in subnanometer channels.

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KW - IR-75519

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DO - 10.1021/ja801178p

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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