Microkinetic and spectroscopic analysis of skeletal isomerization of linear butenes were performed over H-FER. The effect of butene partial pressure and the rate of formation of isobutene and major byproducts are reported. Results show zero order dependence of isobutene production and first order dependence of byproduct formation with butene pressure. Biphenyl type molecules are proposed as coke species and related to byproduct formation.
|Number of pages
|Studies in surface science and catalysis
|Published - 2000
|12th International Congress on Catalysis, ICC 2000 - Granada, Spain
Duration: 9 Jul 2000 → 14 Jul 2000
Conference number: 12