Transition state and diffusion controlled selectivity in skeletal isomerization of olefins

L. Domokos; M.C. Paganini; F.C. Meunier; K. Seshan; J.A. Lercher

doi:10.1016/S0167-2991(00)80977-5

Transition state and diffusion controlled selectivity in skeletal isomerization of olefins

L. Domokos, M.C. Paganini, F.C. Meunier, K. Seshan, J.A. Lercher

Catalytic Processes and Materials

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5 Citations (Scopus)

Abstract

Microkinetic and spectroscopic analysis of skeletal isomerization of linear butenes were performed over H-FER. The effect of butene partial pressure and the rate of formation of isobutene and major byproducts are reported. Results show zero order dependence of isobutene production and first order dependence of byproduct formation with butene pressure. Biphenyl type molecules are proposed as coke species and related to byproduct formation.

Original language	English
Pages (from-to)	323-328
Number of pages	6
Journal	Studies in surface science and catalysis
Volume	130
DOIs	https://doi.org/10.1016/S0167-2991(00)80977-5
Publication status	Published - 2000
Event	12th International Congress on Catalysis, ICC 2000 - Granada, Spain Duration: 9 Jul 2000 → 14 Jul 2000 Conference number: 12

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10.1016/S0167-2991(00)80977-5

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title = "Transition state and diffusion controlled selectivity in skeletal isomerization of olefins",

abstract = "Microkinetic and spectroscopic analysis of skeletal isomerization of linear butenes were performed over H-FER. The effect of butene partial pressure and the rate of formation of isobutene and major byproducts are reported. Results show zero order dependence of isobutene production and first order dependence of byproduct formation with butene pressure. Biphenyl type molecules are proposed as coke species and related to byproduct formation.",

author = "L. Domokos and M.C. Paganini and F.C. Meunier and K. Seshan and J.A. Lercher",

year = "2000",

doi = "10.1016/S0167-2991(00)80977-5",

language = "English",

volume = "130",

pages = "323--328",

journal = "Studies in surface science and catalysis",

issn = "0167-2991",

publisher = "Elsevier Inc.",

note = "12th International Congress on Catalysis, ICC 2000, ICC ; Conference date: 09-07-2000 Through 14-07-2000",

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TY - JOUR

T1 - Transition state and diffusion controlled selectivity in skeletal isomerization of olefins

AU - Domokos, L.

AU - Paganini, M.C.

AU - Meunier, F.C.

AU - Seshan, K.

AU - Lercher, J.A.

N1 - Conference code: 12

PY - 2000

Y1 - 2000

N2 - Microkinetic and spectroscopic analysis of skeletal isomerization of linear butenes were performed over H-FER. The effect of butene partial pressure and the rate of formation of isobutene and major byproducts are reported. Results show zero order dependence of isobutene production and first order dependence of byproduct formation with butene pressure. Biphenyl type molecules are proposed as coke species and related to byproduct formation.

AB - Microkinetic and spectroscopic analysis of skeletal isomerization of linear butenes were performed over H-FER. The effect of butene partial pressure and the rate of formation of isobutene and major byproducts are reported. Results show zero order dependence of isobutene production and first order dependence of byproduct formation with butene pressure. Biphenyl type molecules are proposed as coke species and related to byproduct formation.

U2 - 10.1016/S0167-2991(00)80977-5

DO - 10.1016/S0167-2991(00)80977-5

M3 - Article

SN - 0167-2991

VL - 130

SP - 323

EP - 328

JO - Studies in surface science and catalysis

JF - Studies in surface science and catalysis

T2 - 12th International Congress on Catalysis, ICC 2000

Y2 - 9 July 2000 through 14 July 2000

ER -

Transition state and diffusion controlled selectivity in skeletal isomerization of olefins

Abstract

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