Two-phase (bio)catalytic reactions in a table-top centrifugal contact separator

Gerard N. Kraai; Floris Van Zwol; Boelo Schuur; Hero J. Heeres; Johannes G. De Vries

doi:10.1002/anie.200705426

Two-phase (bio)catalytic reactions in a table-top centrifugal contact separator

Gerard N. Kraai
, Floris Van Zwol
, Boelo Schuur
, Hero J. Heeres
, Johannes G. De Vries (Corresponding Author)

Research output: Contribution to journal › Article › Academic › peer-review

43 Citations (Scopus)

Abstract

(Figure Presented) A new spin on catalysis: A table-top centrifugal contact separator allows for fast continuous two-phase reactions to be performed by intimately mixing two immiscible phases and then separating them. Such a device has been used to produce biodiesel from sunflower oil and MeOH/NaOMe. A lipase-catalyzed esterification of oleic acid with nBuOH (see picture) also proceeds with high conversion and can be run for up to 13 h.

Original language	English
Pages (from-to)	3905-3908
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	21
DOIs	https://doi.org/10.1002/anie.200705426
Publication status	Published - 13 May 2008
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Biphasic catalysis
Enzyme catalysis
Esterification
Fatty acids
Sustainable chemistry

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10.1002/anie.200705426

Cite this

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title = "Two-phase (bio)catalytic reactions in a table-top centrifugal contact separator",

abstract = "(Figure Presented) A new spin on catalysis: A table-top centrifugal contact separator allows for fast continuous two-phase reactions to be performed by intimately mixing two immiscible phases and then separating them. Such a device has been used to produce biodiesel from sunflower oil and MeOH/NaOMe. A lipase-catalyzed esterification of oleic acid with nBuOH (see picture) also proceeds with high conversion and can be run for up to 13 h.",

keywords = "Biphasic catalysis, Enzyme catalysis, Esterification, Fatty acids, Sustainable chemistry",

author = "Kraai, \{Gerard N.\} and \{Van Zwol\}, Floris and Boelo Schuur and Heeres, \{Hero J.\} and \{De Vries\}, \{Johannes G.\}",

year = "2008",

month = may,

day = "13",

doi = "10.1002/anie.200705426",

language = "English",

volume = "47",

pages = "3905--3908",

journal = "Angewandte Chemie - International Edition",

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T1 - Two-phase (bio)catalytic reactions in a table-top centrifugal contact separator

AU - Kraai, Gerard N.

AU - Van Zwol, Floris

AU - Schuur, Boelo

AU - Heeres, Hero J.

AU - De Vries, Johannes G.

PY - 2008/5/13

Y1 - 2008/5/13

N2 - (Figure Presented) A new spin on catalysis: A table-top centrifugal contact separator allows for fast continuous two-phase reactions to be performed by intimately mixing two immiscible phases and then separating them. Such a device has been used to produce biodiesel from sunflower oil and MeOH/NaOMe. A lipase-catalyzed esterification of oleic acid with nBuOH (see picture) also proceeds with high conversion and can be run for up to 13 h.

AB - (Figure Presented) A new spin on catalysis: A table-top centrifugal contact separator allows for fast continuous two-phase reactions to be performed by intimately mixing two immiscible phases and then separating them. Such a device has been used to produce biodiesel from sunflower oil and MeOH/NaOMe. A lipase-catalyzed esterification of oleic acid with nBuOH (see picture) also proceeds with high conversion and can be run for up to 13 h.

KW - Biphasic catalysis

KW - Enzyme catalysis

KW - Esterification

KW - Fatty acids

KW - Sustainable chemistry

UR - https://www.scopus.com/pages/publications/47049093057

U2 - 10.1002/anie.200705426

DO - 10.1002/anie.200705426

M3 - Article

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AN - SCOPUS:47049093057

SN - 1433-7851

VL - 47

SP - 3905

EP - 3908

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 21

ER -

Two-phase (bio)catalytic reactions in a table-top centrifugal contact separator

Abstract

UN SDGs

Keywords

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