Ultradense polymer brushes by adsorption

Wiebe M. De Vos; J. Mieke Kleijn; Arie De Keizer; Martien A.Cohen Stuart

doi:10.1002/anie.200902189

Ultradense polymer brushes by adsorption

Wiebe M. De Vos
, J. Mieke Kleijn
, Arie De Keizer
, Martien A.Cohen Stuart

Research output: Contribution to journal › Article › Academic › peer-review

25 Citations (Scopus)

Abstract

Standing room only: Dense polymer brushes can be prepared by adsorbing a diblock copolymer comprising a neutral block and a polyelectrolyte block to an oppositely charged polyelectrolyte brush (see picture). The density of the resulting neutral brush is determined by charge compensation, leading to brush densities well over 1 nm^-2. The diblock copolymer can be desorbed by changing the solution conditions.

Original language	English
Pages (from-to)	5369-5371
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	29
DOIs	https://doi.org/10.1002/anie.200902189
Publication status	Published - 6 Jul 2009
Externally published	Yes

Keywords

Adsorption
Block copolymers
Complex coacervation
Polymer brushes
Self-assembly

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10.1002/anie.200902189

Cite this

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abstract = "Standing room only: Dense polymer brushes can be prepared by adsorbing a diblock copolymer comprising a neutral block and a polyelectrolyte block to an oppositely charged polyelectrolyte brush (see picture). The density of the resulting neutral brush is determined by charge compensation, leading to brush densities well over 1 nm-2. The diblock copolymer can be desorbed by changing the solution conditions.",

keywords = "Adsorption, Block copolymers, Complex coacervation, Polymer brushes, Self-assembly",

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AU - De Vos, Wiebe M.

AU - Kleijn, J. Mieke

AU - De Keizer, Arie

AU - Stuart, Martien A.Cohen

PY - 2009/7/6

Y1 - 2009/7/6

N2 - Standing room only: Dense polymer brushes can be prepared by adsorbing a diblock copolymer comprising a neutral block and a polyelectrolyte block to an oppositely charged polyelectrolyte brush (see picture). The density of the resulting neutral brush is determined by charge compensation, leading to brush densities well over 1 nm-2. The diblock copolymer can be desorbed by changing the solution conditions.

AB - Standing room only: Dense polymer brushes can be prepared by adsorbing a diblock copolymer comprising a neutral block and a polyelectrolyte block to an oppositely charged polyelectrolyte brush (see picture). The density of the resulting neutral brush is determined by charge compensation, leading to brush densities well over 1 nm-2. The diblock copolymer can be desorbed by changing the solution conditions.

KW - Adsorption

KW - Block copolymers

KW - Complex coacervation

KW - Polymer brushes

KW - Self-assembly

UR - https://www.scopus.com/pages/publications/70349920799

U2 - 10.1002/anie.200902189

DO - 10.1002/anie.200902189

M3 - Article

AN - SCOPUS:70349920799

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -

Ultradense polymer brushes by adsorption

Abstract

Keywords

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