Understanding the unique paradigm in the extraction of tri- And tetravalent actinide/lanthanide ions by a diglycolamide-functionalized dendrimer in RTIL medium

Arunasis Bhattacharyya; Avinash S. Kanekar; Prasanta K. Mohapatra; Andrea Leoncini; Jurriaan Huskens; Willem Verboom

doi:10.1039/d1nj04814g

Understanding the unique paradigm in the extraction of tri- And tetravalent actinide/lanthanide ions by a diglycolamide-functionalized dendrimer in RTIL medium

Arunasis Bhattacharyya
, Avinash S. Kanekar
, Prasanta K. Mohapatra^*
, Andrea Leoncini
, Jurriaan Huskens
, Willem Verboom^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

3 Citations (Scopus)

100 Downloads (Pure)

Abstract

A dendrimer of tris(2-aminoethyl)amine (TREN), containing six diglycolamide (DGA) pendent arms (TREN-G1-DGA), was evaluated for the extraction of different actinides and Eu3+ ions in a methylimidazolium-based room temperature ionic liquid (RTIL; C4mim·NTf2). The results indicated a significant enhancement of the extraction of the trivalent metal ions Am3+ and Eu3+ in the RTIL medium as compared to that in molecular diluents, whereas in the case of the tetravalent actinides Pu4+ and Np4+ the extraction was least affected by the diluent media. This is explained based on a different extraction mechanism for the trivalent and the tetravalent metal ions. The extraction behaviour was well corroborated with the help of a luminescence study.

Original language	English
Pages (from-to)	22044-22048
Number of pages	5
Journal	New journal of chemistry
Volume	45
Issue number	47
Early online date	12 Nov 2021
DOIs	https://doi.org/10.1039/d1nj04814g
Publication status	Published - 21 Dec 2021

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2022 OA procedure

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10.1039/d1nj04814g

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title = "Understanding the unique paradigm in the extraction of tri- And tetravalent actinide/lanthanide ions by a diglycolamide-functionalized dendrimer in RTIL medium",

abstract = "A dendrimer of tris(2-aminoethyl)amine (TREN), containing six diglycolamide (DGA) pendent arms (TREN-G1-DGA), was evaluated for the extraction of different actinides and Eu3+ ions in a methylimidazolium-based room temperature ionic liquid (RTIL; C4mim·NTf2). The results indicated a significant enhancement of the extraction of the trivalent metal ions Am3+ and Eu3+ in the RTIL medium as compared to that in molecular diluents, whereas in the case of the tetravalent actinides Pu4+ and Np4+ the extraction was least affected by the diluent media. This is explained based on a different extraction mechanism for the trivalent and the tetravalent metal ions. The extraction behaviour was well corroborated with the help of a luminescence study.",

keywords = "2022 OA procedure",

author = "Arunasis Bhattacharyya and Kanekar, \{Avinash S.\} and Mohapatra, \{Prasanta K.\} and Andrea Leoncini and Jurriaan Huskens and Willem Verboom",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.",

year = "2021",

month = dec,

day = "21",

doi = "10.1039/d1nj04814g",

language = "English",

volume = "45",

pages = "22044--22048",

journal = "New journal of chemistry",

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Understanding the unique paradigm in the extraction of tri- And tetravalent actinide/lanthanide ions by a diglycolamide-functionalized dendrimer in RTIL medium. / Bhattacharyya, Arunasis; Kanekar, Avinash S.; Mohapatra, Prasanta K. et al.
In: New journal of chemistry, Vol. 45, No. 47, 21.12.2021, p. 22044-22048.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Understanding the unique paradigm in the extraction of tri- And tetravalent actinide/lanthanide ions by a diglycolamide-functionalized dendrimer in RTIL medium

AU - Bhattacharyya, Arunasis

AU - Kanekar, Avinash S.

AU - Mohapatra, Prasanta K.

AU - Leoncini, Andrea

AU - Huskens, Jurriaan

AU - Verboom, Willem

PY - 2021/12/21

Y1 - 2021/12/21

N2 - A dendrimer of tris(2-aminoethyl)amine (TREN), containing six diglycolamide (DGA) pendent arms (TREN-G1-DGA), was evaluated for the extraction of different actinides and Eu3+ ions in a methylimidazolium-based room temperature ionic liquid (RTIL; C4mim·NTf2). The results indicated a significant enhancement of the extraction of the trivalent metal ions Am3+ and Eu3+ in the RTIL medium as compared to that in molecular diluents, whereas in the case of the tetravalent actinides Pu4+ and Np4+ the extraction was least affected by the diluent media. This is explained based on a different extraction mechanism for the trivalent and the tetravalent metal ions. The extraction behaviour was well corroborated with the help of a luminescence study.

AB - A dendrimer of tris(2-aminoethyl)amine (TREN), containing six diglycolamide (DGA) pendent arms (TREN-G1-DGA), was evaluated for the extraction of different actinides and Eu3+ ions in a methylimidazolium-based room temperature ionic liquid (RTIL; C4mim·NTf2). The results indicated a significant enhancement of the extraction of the trivalent metal ions Am3+ and Eu3+ in the RTIL medium as compared to that in molecular diluents, whereas in the case of the tetravalent actinides Pu4+ and Np4+ the extraction was least affected by the diluent media. This is explained based on a different extraction mechanism for the trivalent and the tetravalent metal ions. The extraction behaviour was well corroborated with the help of a luminescence study.

KW - 2022 OA procedure

UR - https://www.scopus.com/pages/publications/85121044432

U2 - 10.1039/d1nj04814g

DO - 10.1039/d1nj04814g

M3 - Article

AN - SCOPUS:85121044432

SN - 1144-0546

VL - 45

SP - 22044

EP - 22048

JO - New journal of chemistry

JF - New journal of chemistry

IS - 47

ER -

Understanding the unique paradigm in the extraction of tri- And tetravalent actinide/lanthanide ions by a diglycolamide-functionalized dendrimer in RTIL medium

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