Upscaling of a Batch De-vulcanization Process for Ground Car Tire Rubber to a Continuous Process in a Twin Screw Extruder

Sitisaiyidah Saiwari, Johannes W. van Hoek, Wilma K. Dierkes, Louis A.E.M. Reuvekamp, Geert Heideman, Anke Blume, Jacobus W.M. Noordermeer

Research output: Contribution to journalArticleAcademicpeer-review

9 Citations (Scopus)
99 Downloads (Pure)

Abstract

As a means to decrease the amount of waste tires and to re-use tire rubber for new tires, devulcanization of ground passenger car tires is a promising process. Being an established process for NR and EPDM, earlier work has shown that for ground passenger car tire rubber with a relatively high amount of SBR, a devulcanization process can be formulated, as well. This was proven for a laboratory-scale batch process in an internal mixer, using diphenyl disulfide as the devulcanization aid and powder-sized material. In this paper, the devulcanization process for passenger car tire rubber is upscaled from 15 g per batch and transformed into a continuous process in a co-rotating twin screw extruder with a capacity of 2 kg/h. As SBR is rather sensitive to devulcanization process conditions, such as thermal and mechanical energy input, the screw design was based on a low shear concept. A granulate with particle sizes from 1–3.5 mm was chosen for purity, as well as economic reasons. The devulcanization process conditions were fine-tuned in terms of: devulcanization conditions (time/temperature profile, concentration of devulcanization aid), extruder parameters (screw configuration, screw speed, fill factor) and ancillary equipment (pre-treatment, extrudate handling). The influence of these parameters on the devulcanization efficiency and the quality of the final product will be discussed. The ratio of random to crosslink scission as determined by a Horikx plot was taken for the evaluation of the process and material. A best practice for continuous devulcanization will be given.
Original languageEnglish
Article number724
Number of pages17
JournalMaterials
Volume9
Issue number9
DOIs
Publication statusPublished - 24 Aug 2016

Keywords

  • Devulcanization
  • Tire
  • Twin-screw extruder
  • DPDS
  • Low shear
  • Thermo chemical
  • Horikx

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