Water-Induced Blister Formation in a Thin Film Polymer

R.P. Berkelaar; Pantelis Bampoulis; E. Dietrich; H.P. Jansen; Xuehua Zhang; E. Stefan Kooij; Detlef Lohse; Harold J.W. Zandvliet

doi:10.1021/la504002w

Water-Induced Blister Formation in a Thin Film Polymer

R.P. Berkelaar, Pantelis Bampoulis, E. Dietrich, H.P. Jansen, Xuehua Zhang, E. Stefan Kooij, Detlef Lohse, Harold J.W. Zandvliet

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Abstract

A failure mechanism of thin film polymers immersed in water is presented: the formation of blisters. The growth of blisters is counterintuitive as the substrates were noncorroding and the polymer does not swell in water. We identify osmosis as the driving force behind the blister formation. The dynamics of the blister formation is studied experimentally as well as theoretically, and a quantitative model describing the blister growth is developed, which accurately describes the temporal evolution of the blisters.

Original language	English
Pages (from-to)	1017-1025
Number of pages	9
Journal	Langmuir
Volume	31
Issue number	3
DOIs	https://doi.org/10.1021/la504002w
Publication status	Published - 2015

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10.1021/la504002w

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title = "Water-Induced Blister Formation in a Thin Film Polymer",

abstract = "A failure mechanism of thin film polymers immersed in water is presented: the formation of blisters. The growth of blisters is counterintuitive as the substrates were noncorroding and the polymer does not swell in water. We identify osmosis as the driving force behind the blister formation. The dynamics of the blister formation is studied experimentally as well as theoretically, and a quantitative model describing the blister growth is developed, which accurately describes the temporal evolution of the blisters.",

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author = "R.P. Berkelaar and Pantelis Bampoulis and E. Dietrich and H.P. Jansen and Xuehua Zhang and Kooij, {E. Stefan} and Detlef Lohse and Zandvliet, {Harold J.W.}",

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AU - Berkelaar, R.P.

AU - Bampoulis, Pantelis

AU - Dietrich, E.

AU - Jansen, H.P.

AU - Zhang, Xuehua

AU - Kooij, E. Stefan

AU - Lohse, Detlef

AU - Zandvliet, Harold J.W.

PY - 2015

Y1 - 2015

N2 - A failure mechanism of thin film polymers immersed in water is presented: the formation of blisters. The growth of blisters is counterintuitive as the substrates were noncorroding and the polymer does not swell in water. We identify osmosis as the driving force behind the blister formation. The dynamics of the blister formation is studied experimentally as well as theoretically, and a quantitative model describing the blister growth is developed, which accurately describes the temporal evolution of the blisters.

AB - A failure mechanism of thin film polymers immersed in water is presented: the formation of blisters. The growth of blisters is counterintuitive as the substrates were noncorroding and the polymer does not swell in water. We identify osmosis as the driving force behind the blister formation. The dynamics of the blister formation is studied experimentally as well as theoretically, and a quantitative model describing the blister growth is developed, which accurately describes the temporal evolution of the blisters.

KW - 22/4 OA procedure

U2 - 10.1021/la504002w

DO - 10.1021/la504002w

M3 - Article

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EP - 1025

JO - Langmuir

JF - Langmuir

SN - 0743-7463

IS - 3

ER -

Water-Induced Blister Formation in a Thin Film Polymer

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