Water-soluble neutral calix[4]arene-lanthanide complexes: synthesis and luminescence properties

F.J. Steemers; Frank J. Steemers; Hans G. Meuris; Willem Verboom; David Reinhoudt; Eric B. van der Tol; Jan W. Verhoeven

doi:10.1021/jo970132j

Water-soluble neutral calix[4]arene-lanthanide complexes: synthesis and luminescence properties

F.J. Steemers, Frank J. Steemers, Hans G. Meuris, Willem Verboom, David Reinhoudt, Eric B. van der Tol, Jan W. Verhoeven

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Abstract

Water-soluble calix[4]arenes 10a,b with chromophores ("antenna") attached to the lower rim via a short spacer are described. In the neutral lanthanide complexes of 10a,b photoexcitation of the antenna induces lanthanide emission via intramolecular energy transfer. Calix[4]arene 10b with a chrysene moiety as sensitizer shows strong lanthanide emission for Eu3+ with an excitation maximum at ^ = 363 nm.

Original language	Undefined
Pages (from-to)	4229-4235
Journal	The journal of organic chemistry
Volume	62
Issue number	62
DOIs	https://doi.org/10.1021/jo970132j
Publication status	Published - 1997

Keywords

METIS-106005
IR-11123

Access to Document

10.1021/jo970132j

K11123__

Cite this

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abstract = "Water-soluble calix[4]arenes 10a,b with chromophores ({"}antenna{"}) attached to the lower rim via a short spacer are described. In the neutral lanthanide complexes of 10a,b photoexcitation of the antenna induces lanthanide emission via intramolecular energy transfer. Calix[4]arene 10b with a chrysene moiety as sensitizer shows strong lanthanide emission for Eu3+ with an excitation maximum at ^ = 363 nm.",

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author = "F.J. Steemers and Steemers, {Frank J.} and Meuris, {Hans G.} and Willem Verboom and David Reinhoudt and {van der Tol}, {Eric B.} and Verhoeven, {Jan W.}",

year = "1997",

doi = "10.1021/jo970132j",

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T1 - Water-soluble neutral calix[4]arene-lanthanide complexes: synthesis and luminescence properties

AU - Steemers, F.J.

AU - Steemers, Frank J.

AU - Meuris, Hans G.

AU - Verboom, Willem

AU - Reinhoudt, David

AU - van der Tol, Eric B.

AU - Verhoeven, Jan W.

PY - 1997

Y1 - 1997

N2 - Water-soluble calix[4]arenes 10a,b with chromophores ("antenna") attached to the lower rim via a short spacer are described. In the neutral lanthanide complexes of 10a,b photoexcitation of the antenna induces lanthanide emission via intramolecular energy transfer. Calix[4]arene 10b with a chrysene moiety as sensitizer shows strong lanthanide emission for Eu3+ with an excitation maximum at ^ = 363 nm.

AB - Water-soluble calix[4]arenes 10a,b with chromophores ("antenna") attached to the lower rim via a short spacer are described. In the neutral lanthanide complexes of 10a,b photoexcitation of the antenna induces lanthanide emission via intramolecular energy transfer. Calix[4]arene 10b with a chrysene moiety as sensitizer shows strong lanthanide emission for Eu3+ with an excitation maximum at ^ = 363 nm.

KW - METIS-106005

KW - IR-11123

U2 - 10.1021/jo970132j

DO - 10.1021/jo970132j

M3 - Article

SN - 0022-3263

VL - 62

SP - 4229

EP - 4235

JO - The journal of organic chemistry

JF - The journal of organic chemistry

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ER -